L-Aspartate links for stable sodium metal-organic frameworks.

نویسندگان

  • Peter Siman
  • Christopher A Trickett
  • Hiroyasu Furukawa
  • Omar M Yaghi
چکیده

Metal-organic frameworks (MOFs) based purely on sodium are rare, typically due to large numbers of coordinating solvent ligands. We designed a tetratopic aspartate-based linker with flexible carboxylate groups to enhance framework stability. We report two new air-stable sodium MOFs, MOF-705 and MOF-706, comprising 2D sodium oxide sheets.

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عنوان ژورنال:
  • Chemical communications

دوره 51 98  شماره 

صفحات  -

تاریخ انتشار 2015